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Glossary

Isomerisation

The heat-driven rearrangement of hop alpha acids into iso-alpha-acids, which unlike their precursors are both bitter and soluble in beer.

Pronounced eye-SOM-er-eye-ZAY-shun.

Also called isomerization, iso-alpha-acid, iso alpha acids.

This is why hops must be boiled to bitter beer. Raw alpha acids are barely soluble and barely bitter; the isomerised form is both. The reaction is slow, which is why bittering hops go in at the start of a 60-minute boil and aroma hops added at the end contribute almost no bitterness.

It is also why dry hopping adds aroma but essentially no bitterness — there is no heat to drive the rearrangement.

Related

  • Alpha acidThe precursor.
  • IBUThe measure of the product.
  • Dry hoppingThe technique that deliberately avoids it.

More vocabulary

Arrested fermentation · Barrel ageing · Batch sparging · Biotransformation · Blending · Bottle conditioning · Bottom fermentation · Burtonisation · Cask conditioning · Centrifugation

See every term on the glossary index.

Last reviewed 2026-08-16.